AC impedance method is a very important method in electrochemical testing technology, which is an important means of studying electrode process dynamics and surface phenomena. Especially in recent years, due to the rapid development of frequency response analyzers, the testing accuracy of AC impedance has become higher and higher, and the impedance spectrum of ultra-low frequency signals has good reproducibility. In addition, with the advancement of computer technology, the automation of impedance spectrum analysis has become higher and higher. This enables us to better understand the double layer structure of electrode surfaces, activate passivation film conversion, induce, develop, terminate pore corrosion, and the adsorption and desorption process of active substances.
Both the linear polarization of the triangular wave scan and the linear polarization of the sine wave scan are based on the electrochemical linear polarization principle to measure the polarization resistance of the electrode system, and the polarization potential range of both is within the linear range (± 10mV OCP). Triangular wave scanning linear polarization is to apply a triangular wave scanning signal based on potential or current control to the system, and its scanning rate is generally 0.5mV/s to 5mV/s, and the polarization resistance Rp is calculated by dividing the polarization potential DE by the slope of the polarization current DI. Then the polarization current density Icorr is calculated according to Stern equation (2)